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铸(Zhu)造(Zao)铝(Lu)合(He)金(Jin)阳(Yang)极(Ji)氧(Yang)化(Hua)

铸(Zhu)造(Zao)铝(Lu)合(He)金(Jin)阳(Yang)极(Ji)氧(Yang)化(Hua)

铸(Zhu)造(Zao)铝(Lu)合(He)金(Jin)阳(Yang)极(Ji)氧(Yang)化(Hua)是(Shi)在(Zai)含(Han)有(You)氧(Yang)化(Hua)剂(Ji)的(De)弱(Ruo)酸(Suan)性(Xing)或(Huo)弱(Ruo)碱(Jian)性(Xing)溶(Rong)液(Ye)中(Zhong)进(Jin)行(Xing),(?)在(Zai)弱(Ruo)碱(Jian)性(Xing)溶(Rong)液(Ye)中(Zhong)A13+与(Yu)溶(Rong)液(Ye)中(Zhong)的(De)OH-构(Gou)成(Cheng)可(Ke)溶(Rong)性(Xing)的(De)Al00H,(?)然(Ran)后(Hou)转(Zhuan)化(Hua)尴(Gan)尬( ga)溶(Rong)的(De)r一(Yi)Al203·(?)H20附(Fu)着(Zhuo)在(Zai)铝(Lu)及(Ji)铝(Lu)合(He)金(Jin)的(De)表(Biao)面(Mian);在(Zai)含(Han)有(You)磷(Lin)酸(Suan)、(?)铬(Ge)酸(Suan)和(He)氟(Fu)化(Hua)物(Wu)的(De)弱(Ruo)酸(Suan)性(Xing)溶(Rong)液(Ye)中(Zhong),(?)Al与(Yu)H3P04、(?)Cr2072-反(Fan)响(Xiang)生(Sheng)成(Cheng)Al203及(Ji)AlP04、(?)CrP04薄(Bao)膜(Mo)。(?)

    由(You)化(Hua)学(Xue)反(Fan)响(Xiang)生(Sheng)成(Cheng)的(De)膜(Mo)厚(Hou)达(Da)必(Bi)定(Ding)值(Zhi)(0.5~(?)4μ(?)m)时(Shi),(?)因(Yin)为(Wei)膜(Mo)无(Wu)松(Song)孔(Kong),(?)阻(Zu)止(Zhi)了(Liao)溶(Rong)液(Ye)与(Yu)基(Ji)体(Ti)金(Jin)属(Shu)的(De)触(Chu)摸(Mo),(?)使(Shi)膜(Mo)成(Cheng)长(Chang)中(Zhong)止(Zhi),(?)为(Wei)了(Liao)坚(Jian)持(Chi)必(Bi)定(Ding)的(De)孔(Kong)隙(Xi),(?)使(Shi)膜(Mo)持(Chi)续(Xu)增(Zeng)厚(Hou),(?)需(Xu)向(Xiang)溶(Rong)液(Ye)中(Zhong)参(Can)加(Jia)弱(Ruo)酸(Suan)或(Huo)弱(Ruo)碱(Jian),(?)所(Suo)以(Yi)酸(Suan)和(He)碱(Jian)是(Shi)化(Hua)学(Xue)氧(Yang)化(Hua)成(Cheng)膜(Mo)的(De)主(Zhu)要(Yao)成(Cheng)分(Fen);再(Zai)者(Zhe),(?)为(Wei)了(Liao)按(An)捺(Na)酸(Suan)和(He)碱(Jian)对(Dui)膜(Mo)的(De)过(Guo)度(Du)溶(Rong)解(Jie)腐(Fu)蚀(Shi),(?)还(Huan)向(Xiang)溶(Rong)液(Ye)中(Zhong)参(Can)加(Jia)氧(Yang)化(Hua)剂(Ji)铬(Ge)酐(Gan)或(Huo)铬(Ge)酸(Suan)盐(Yan),(?)使(Shi)膜(Mo)的(De)成(Cheng)长(Chang)和(He)溶(Rong)解(Jie)坚(Jian)持(Chi)必(Bi)定(Ding)的(De)平(Ping)衡(Heng),(?)以(Yi)到(Dao)达(Da)较(Jiao)厚(Hou)的(De)膜(Mo)层(Ceng)(碱(Jian)性(Xing)液(Ye)中(Zhong)厚(Hou)度(Du)可(Ke)到(Dao)达(Da)2~(?)39m;酸(Suan)性(Xing)溶(Rong)液(Ye)中(Zhong)厚(Hou)度(Du)可(Ke)到(Dao)达(Da)3~(?)4μ(?)m)。(?)



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